with x \in [0 , 2 \pi] and \hbar = 1.
When \eqref{eq:20170129a} is solved in physics books, it is usually imposed that the wave function should be periodic [1]. I used to be puzzled why one has to impose the periodicity.
After all, I thought, only the probability density function |\psi|^2 has physical meaning, so one could as well impose that
\begin{equation}\label{eq:20170129b}
\psi(2 \pi) = e^{ i \alpha} \psi(0) \quad\text{with}\quad \alpha\in\mathbb{R}
\end{equation}
A first answer to my puzzle is
The definition of the Hilbert space \mathcal{H} is part of the specification of the quantum system. Hence, if \mathcal{H} is the
space of square-integrable functions on the circle, then \mathcal{H} contains functions, hence e^{ i \alpha} should be equal to 1 because otherwise \psi
is not a function.
A second answer is as follows. Suppose I leave the exact definition of \mathcal{H} open for now, but impose the condition \eqref{eq:20170129b}. Then \eta defined by \begin{equation}\label{eq:20170129c} \eta(t,x) = e^{ - i \alpha \dfrac{x}{2 \pi}} \psi(t,x) \end{equation}
is periodic, therefore \eta is a function on the circle.
Furthermore \eta satisfies
\begin{equation}\label{eq:20170129d}
i \frac{\partial \eta}{\partial t} = - \frac{1}{2 m} \left( \partial_x + i \frac{\alpha}{2 \pi} \right)^2\eta
\end{equation}
This is the Schrödinger equation of a particle on a circle with constant vector potential A = \frac{\alpha}{2 \pi} dx. Therefore, the second answer to the puzzle is
Yes, one can impose the condition \eqref{eq:20170129b}. The Hilbert space is then not the space of square integrable functions [2].
Hence the physical system is different, namely, it is a particle on a circle with Wilson loop.
I was motivated to write this post when I was reading the famous article by Dirac about magnetic monopoles [3] and section 18.3 in [4].
References and comments
[1] For example, exercise 2.43 in Griffiths, Introduction to Quantum Mechanics
[2] The Hilbert space is the set of square integrable sections of some kind of bundle over the circle.
[3] A.M. Dirac "Quantised Singularities in the Electromagnetic Field", 1931. Journal Site, pdf file
[4] A First Course in String Theory, Zwiebach, 2009
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