The Hamiltonian of the three-dimensional harmonic oscillator is (setting $\hbar=m=\omega = 1$ for simplicity) \begin{equation*} H = \frac{1}{2} \vec{p}^2 + \frac{1}{2} r^2 \end{equation*} with $r^2 = x^2 + y^2 + z^2$. The energy levels are of the form [1] \begin{equation*} E_n = n + 3/2 \end{equation*} with $n \ge 0$ an integer. The degeneracy of the $n$-th level $d(n)$ is equal to the number of ways $n$ can be written as $n = n_1 + n_2 + n_3$ where $0 \le n_1, n_2, n_3 $ are integers. For example,
- If $n=0$, $d(0)=1$ because one only has $0 = 0+0+0$
- If $n=1$, $d(1)=3$ because one has the three possibilities \begin{align*} 1 &= 1+0+0\\ 1 &= 0+1+0\\ 1 &= 0+0+1 \end{align*}
- The case $n=2$ is already more interesting. $d(2) = 6$ coming from \begin{align*} 2 &= 2+0+0\\ 2 &= 0+2+0\\ 2 &= 0+0+2\\ 2 &= 1+1+0\\ 2 &= 1+0+1\\ 2 &= 0+1+1 \end{align*} Here one can calculate that the states transform under $SO(3)$ as the representation $\bf{5} + \bf{1}$. There is thus a degeneracy in the energy levels that is not explained by the $SO(3)$ symmetry.
- At the next level, there is even more degeneracy: $d(3) = 10$ coming from \begin{align*} 3 &= 3+0+0,\quad\text{3 permutations in total}\\ 3 &= 2+1+0,\quad\text{6 permutations in total}\\ 3 &= 1+1+1\end{align*} Here one can calculate that the states transform under $SO(3)$ as the representation $\bf{7} + \bf{3}$.
References
[1] Griffiths, Introduction to Quantum Mechanics, exercise 4.39
[2] Georgi, Lie Algebras In Particle Physics
[3] Kirson, Isotropic harmonic oscillator
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